Showing posts with label carbon. Show all posts
Showing posts with label carbon. Show all posts

Monday, June 25, 2012

Carbon is Key for Getting Algae to Pump Out More Oil

Overturning two long-held misconceptions about oil production in algae, scientists at the U.S. Department of Energy’s Brookhaven National Laboratory show that ramping up the microbes’ overall metabolism by feeding them more carbon increases oil production as the organisms continue to grow. The findings — published online in the journal Plant and Cell Physiology on May 28, 2012 — may point to new ways to turn photosynthetic green algae into tiny “green factories” for producing raw materials for alternative fuels.

“We are interested in algae because they grow very quickly and can efficiently convert carbon dioxide into carbon-chain molecules like starch and oils,” said Brookhaven biologist Changcheng Xu, the paper’s lead author. With eight times the energy density of starch, algal oil in particular could be an ideal raw material for making biodiesel and other renewable fuels.

But there have been some problems turning microscopic algae into oil producing factories.
For one thing, when the tiny microbes take in carbon dioxide for photosynthesis, they preferentially convert the carbon into starch rather than oils. “Normally, algae produce very little oil,” Xu said.

Before the current research, the only way scientists knew to tip the balance in favor of oil production was to starve the algae of certain key nutrients, like nitrogen. Oil output would increase, but the algae would stop growing — not ideal conditions for continuous production.

Another issue was that scientists didn’t know much about the details of oil biochemistry in algae. “Much of what we thought we knew was inferred from studies performed on higher plants,” said Brookhaven biochemist John Shanklin, a co-author who’s conducted extensive research on plant oil production. Recent studies have hinted at big differences between the microbial algae and their more complex photosynthetic relatives.

Jilian Fan, Changcheng Xu, and Chengshi Yan

“Our goal was to learn all we could about the factors that contribute to oil production in algae, including those that control metabolic switching between starch and oil, to see if we could shift the balance to oil production without stopping algae growth,” Xu said.

The scientists grew cultures of Chlamydomonas reinhardtii — the “fruit fly” of algae — under a variety of nutrient conditions, with and without inhibitors that would limit specific biochemical pathways. They also studied a mutant Chlamydomonas that lacks the capacity to make starch. By comparing how much oil accumulated over time in the two strains across the various conditions, they were able to learn why carbon preferentially partitions into starch rather than oil, and how to affect the process.

The main finding was that feeding the algae more carbon (in the form of acetate) quickly maxed out the production of starch to the point that any additional carbon was channeled into high-gear oil production. And, most significantly, under the excess carbon condition and without nutrient deprivation, the microbes kept growing while producing oil.

“This overturns the previously held dogma that algae growth and increased oil production are mutually exclusive,” Xu said.

The detailed studies, conducted mainly by Brookhaven research associates Jilian Fan and Chengshi Yan, showed that the amount of carbon was the key factor determining how much oil was produced: more carbon resulted in more oil; less carbon limited production. This was another surprise because a lot of approaches for increasing oil production have focused on the role of enzymes involved in producing fatty acids and oils. In this study, inhibiting enzyme production had little effect on oil output.

“This is an example of a substantial difference between algae and higher plants,” said Shanklin.
In plants, the enzymes directly involved in the oil biosynthetic pathway are the limiting factors in oil production. In algae, the limiting step is not in the oil biosynthesis itself, but further back in central metabolism.

This is not all that different from what we see in human metabolism, Xu points out: Eating more carbon-rich carbohydrates pushes our metabolism to increase oil (fat) production and storage.

“It’s kind of surprising that, in some ways, we’re more like algae than higher plants are,” Xu said, noting that scientists in other fields may be interested in the details of metabolic switching uncovered by this research.

But the next step for the Brookhaven team will be to look more closely at the differences in carbon partitioning in algae and plants. This part of the work will be led by co-author Jorg Schwender, an expert in metabolic flux studies. The team will also work to translate what they’ve learned in a model algal species into information that can help increase the yield of commercial algal strains for the production of raw materials for biofuels.

Tuesday, April 3, 2012

Poll Shows Carbon Tax Needs Sale of the Century to Change Voters' Views

THE government's task of selling the carbon price to voters when it begins on July 1 remains difficult, with a poll showing entrenched negative attitudes towards the policy.

The latest Herald/Nielsen poll shows support for a price on carbon at 36 per cent, with 60 per cent opposed.

Just over half of voters - 52 per cent - believe they will be worse off, even though low- and middle-income earners will get $15 billion compensation to cover cost-of-living increases.

Another 39 per cent believe it will make no difference to their cost of living, while 5 per cent feel they will be better off.

The poll of 1400 voters was taken from Thursday night to Saturday night last week, after Labor's crushing defeat in the Queensland election.

The Opposition Leader, Tony Abbott, sought to implicate Julia Gillard's broken promise not to introduce a carbon tax as a factor in that defeat.

The numbers in the latest poll have barely changed in more than a year. Before Ms Gillard announced the carbon policy in February last year, the poll found support for putting a price on carbon evenly split. After the announcement - and opposition claims she had broken her promise - support fell to 35 per cent and opposition rose to 56 per cent. The levels have altered little since.

In July, the government revealed details of the household compensation, which will be worth $15 billion in the first four years. It would be paid as tax cuts and welfare and pension increases. In many cases, those on very low incomes would receive more in compensation than their increase in cost of living as estimated by Treasury.

The Herald poll taken then showed 53 per cent felt they would be worse off, 37 per cent felt there would be no change and 6 per cent felt they would be better off. These numbers are almost identical to the latest poll.

Ms Gillard has rejected calls from business to reduce the impact of the carbon price by cutting the fixed starting price of $23 a tonne roughly in half, to bring it in line with the carbon price in Europe.
Yesterday, she said voter anxiety with her government had been fuelled by the Coalition's ''hyper-partisanship''. She said it had ''force-fed for many months a diet of completely outlandish scare campaigns about what carbon pricing is going to mean''.

She repeated that employment would still grow, the cost-of-living impact would be less than 1 per cent and the compensation would be in place.

Mr Abbott has promised that, if elected, his first act as prime minister would be to unwind the price on carbon. Ms Gillard told Channel Ten's Meet the Press program this ''chest-beating'' would ''prove to be incredibly hollow''.

By next year, the carbon price would be a year old, the economy would have started to adjust and ''people would have got the money in their hands''.

''Mr Abbott, I think, will find it very difficult indeed to pretend to the Australian people that he is going to seriously dismantle all that,'' she said.

Tuesday, December 6, 2011

Climategate (Part II) A sequel as ugly as the original.


The conventional wisdom about blockbuster movie sequels is that the second acts are seldom as good as the originals. The exceptions, like The Godfather: Part II or The Empire Strikes Back, succeed because they build a bigger backstory and add dimensions to the original characters. The sudden release last week of another 5,000 emails from the Climate Research Unit (CRU) of East Anglia University​—​ground zero of “Climategate I” in 2009​—​immediately raised the question of whether this would be one of those rare exceptions or Revenge of the Nerds II.

Before anyone had time to get very far into this vast archive, the climate campaigners were ready with their critical review: Nothing worth seeing here. Out of context! Cherry picking! “This is just trivia, it’s a diversion,” climate researcher Joel Smith told Politico. On the other side, Anthony Watts, proprietor of the invaluable WattsUpWithThat.com skeptic website, had the kind of memorable line fit for a movie poster. With a hat tip to the famous Seinfeld episode, Watts wrote: “They’re real, and they’re spectacular!” An extended review of this massive new cache will take months and could easily require a book-length treatment. But reading even a few dozen of the newly leaked emails makes clear that Watts and other longtime critics of the climate cabal are going to be vindicated.

Climategate I, the release of a few thousand emails and documents from the CRU in November 2009, revealed that the united-front clubbiness of the leading climate scientists was just a display for public consumption. The science of climate change was not “settled.” There was no consensus about the extent and causes of global warming; in their private emails, the scientists expressed serious doubts and disagreements on some major issues. In particular, the email exchanges showed that they were far from agreement about a key part of the global warming narrative​—​the famous “hockey stick” graph that purported to demonstrate that the last 30 years were the warmest of the last millennium and which made the “medieval warm period,” an especially problematic phenomenon for the climate campaign, simply go away. (See my “Scientists Behaving Badly,” The Weekly Standard, December 14, 2009.) Leading scientists in the inner circle expressed significant doubts and uncertainty about the hockey stick and several other global warming claims about which we are repeatedly told there exists an ironclad consensus among scientists. (Many of the new emails make this point even more powerfully.) On the merits, the 2009 emails showed that the case for certainty about climate change was grossly overstated.

More damning than the substantive disagreement was the attitude the CRU circle displayed toward dissenters, skeptics, and science journals that did not strictly adhere to the party line. Dissenting articles were blocked from publication or review by the Intergovernmental Panel on Climate Change (IPCC), requests for raw data were rebuffed, and Freedom of Information Act requests were stonewalled. National science panels were stacked, and qualified dissenters such as NASA prize-winner John Christy were tolerated as “token skeptics.” The CRU circle was in high dudgeon over the small handful of skeptics who insisted on looking over their shoulder, revealing the climate science community to be thin-skinned and in-secure about its enterprise​—​a sign that something is likely amiss. Even if there was no unequivocal “smoking gun” of fraud or wrongdoing, the glimpse deep inside the climate science community was devastating. As I wrote at the time (“In Denial,” March 15, 2010), Climategate did for the global warming controversy what the Pentagon Papers did for the Vietnam war 40 years ago: It changed the narrative decisively.

The new batch of emails, over 5,300 in all (compared with about 1,000 in the 2009 release), contains a number of fresh embarrassments and huge red flags for the same lovable bunch of insider scientists. It stars the same cast, starting with the Godfather of the CRU, Phil “hide the decline” Jones, and featuring Michael “hockey stick” Mann once again in his supporting role as the Fredo of climate science, blustering along despite the misgivings and doubts of many of his peers. Beyond the purely human element, the new cache offers ample confirmation of the rank politicization of climate science and rampant cronyism that ought to trouble even firm believers in catastrophic climate change.

In fact, the emails display candid glimpses of concern inside the CRU circle. Peter Thorne of NOAA (National Oceanographic and Atmospheric Administration), who earned his Ph.D. in climate science at East Anglia in 2001, wrote Phil Jones in a 2005 message, “I also think the science is being manipulated to put a political spin on it which for all our sakes might not be too clever in the long run.” An appeal to “context,” which the climate campaigners say is crucial to understanding why excerpts such as this one are unimportant, does quite the opposite, and only points to the problems the climate change campaigners have brought upon themselves by their tribalism.

This exchange between Thorne and Jones, along with numerous similar threads in the new cache, is concerned with what should and shouldn’t be included in a chapter of the IPCC’s 2007 fourth assessment report​—​a chapter for which Jones was the coordinating lead author along with another key Climategate figure, Kevin Trenberth. The complete chapter (if you’re keeping score at home, it’s Chapter 3 of Working Group I, “Observations: Surface and Atmospheric Climate Change”) lists 10 “lead authors” and 66 “contributing authors” in addition to Jones and Trenberth. One of Jones’s emails from 2004 displays how explicitly political the process of assembling the IPCC report is: “We have a very mixed bag of LAs [lead authors] in our chapter. Being the basic atmos obs. one, we’ve picked up number of people from developing countries so IPCC can claim good geographic representation. This has made our task harder as CLAs [contributing lead authors] as we are working with about 50% good people who can write reasonable assessments and 50% who probably can’t.”

The final chapter was amended along lines Thorne recommended, but several other objections and contrary observations (one in particular from Roger Pielke Jr. about extreme weather events that has been subsequently vindicated) were scornfully dismissed. And appeals to context avoid the question: Is this “science-by-committee” a sensible way to sort out contentious scientific issues that hold immense public policy implications? Perhaps a politicized, semi-chaotic process like the IPCC is unavoidable in a subject as wide-ranging and complex as climate change; future historians of science can debate the issue. But the high stakes involved ought to compel a maximum of open debate and transparency. Instead, the IPCC process places a premium on gatekeepers and arbiters who control what goes in and what doesn’t, and it is exactly in its exercise of the gatekeeping function that the CRU circle has shredded its credibility and trustworthiness.

One thing that emerges from the new emails is that, while a large number of scientists are working on separate, detailed nodes of climate-related issues (the reason for dozens of authors for every IPCC report chapter), the circle of scientists who control the syntheses that go into IPCC reports and the national climate reports that the U.S. and other governments occasionally produce is quite small and partial to particular outcomes of these periodic assessments. The way the process works in practice casts a shadow over one of the favorite claims of the climate campaign​—​namely, that there exists a firm “consensus” about catastrophic future warming among thousands of scientists. This so-called consensus reflects only the views of a much smaller subset of gatekeepers.

Beyond additional bad news for the hockey stick graph, is there anything new in these emails about scientific aspects of the issue? This will take time to sort out, but I suspect anyone with the patience to go through the weeds of all 5,300 messages and cross check them against published results may well discover troubling new aspects of how climate modeling is done, and how weak the models still are on crucial points (such as cloud behavior). Some of the new emails frankly acknowledge such problems. There are arcane discussions about how to interpolate gaps in the data, how to harmonize different data sets, and how to resolve the frequent and often inconvenient (because contradictory) anomalies in modeling results. Definite examples of political influence have emerged already from a first pass over a sample of the massive cache.

In the editing process before the IPCC’s 2001 third assessment report, Timothy Carter of the Finnish Environmental Institute wrote in 2000 to three chapter authors with the observation, “It seems that a few people have a very strong say, and no matter how much talking goes on beforehand, the big decisions are made at the eleventh hour by a select core group.” In this case, decisions at the highest levels of what specific figures and conclusions were to appear in the short “summary for policy makers”​—​usually the only part of the IPCC’s multivolume reports that the media and politicians read​—​required changing what appeared in individual chapters, a case of the conclusions driving the findings in the detailed chapters instead of the other way around. This has been a frequent complaint of scientists participating in the IPCC process since the beginning, and the new emails show that even scientists within the “consensus” recognize the problem. Comments such as one from Jonathan Overpeck, writing in 2004 about how to summarize some ocean data in a half-page, reinforce the impression that politics drives the process: “The trick may be to decide on the main message and use that to guid[e] what’s included and what is left out.”

No amount of context can possibly exonerate the CRU gang from some of the damning expressions and contrivances that appear repeatedly in the new emails. More so than the 2009 batch, these emails make clear the close collaboration between the leading IPCC scientists and environmental advocacy groups, government agencies, and partisan journalists. There are repeated instances of scientists tipping their hand that they’ve thrown in their lot with the climate ideologues. If there were only a handful of such dubious messages, they might be explained away through “context,” or as conciliatory habits of expression. But they are so numerous that it doesn’t require an advanced degree in pattern recognition to make out that these emails constitute not just a “smoking gun” of scientific bias, but a belching howitzer. Throughout the emails numerous participants refer to “the cause,” “our cause,” and other nonscientific, value-laden terms to describe the implications of one dispute or another, while demonizing scientists who express even partial dissent about the subject, such as Judith Curry of Georgia Tech.

Since the beginning of the climate change story more than 20 years ago, it has been hard to sort out whether the IPCC represents the “best” science, or merely the findings most compatible with the politically driven climate policy agenda. Both sets of emails have lifted the lid on the insides of the process, and it isn’t pretty.

A good example of how the political-scientific complex works hand-in-glove to tightly control the results comes from May 2009, when the IPCC authors were working on a “weather generator,” which they hoped would produce climate change scenarios tailored to localities, so as to promote favored adaptive measures (sea walls, flood control, drought readiness, etc.).

This is a small but hugely controversial aspect of climate modeling, and one where politicians and advocacy groups (the World Wildlife Fund was especially keen to have this kind of work done) may well be asking scientists to do the impossible. But there’s research money in it, so scientists are only too happy to oblige. Kathryn Humphrey, a science adviser in Britain’s DEFRA (Department of Environment, Forestry, and Rural Affairs​—​Britain’s EPA) wrote a worried note to Phil Jones and several other scientists involved in the project about criticisms of the cloistered working group behind the weather generator scheme, noting, “Ministers have also raised questions about this so we will need to go back to them with some further advice.”

Jones tries to reassure Humphrey that he’s got the working group under control: “As I’ve said on numerous occasions, if the WG [working group] isn’t there, all the people that need [the weather generator] will go off and do their own thing.

This will mean that individual sectors and single studies will do a whole range of different things. This will make the uncertainties even larger!” What Jones is referring to are numerous independent scientific efforts to “downscale” climate models to predict local impacts, and the fact that the results of these separate efforts have been chaotic, rather than demonstrating consensus. Hence the need for someone in authority to marginalize uncertainties and contradictory results. But this is properly called politics, not science.

Read the Rest of this article

Tuesday, August 30, 2011

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